iv. 347 Effective July 1, 2011, for transportation by aircraft, this entry may only be used if the results of Test series 6(d) of Part I of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter) have demonstrated that any hazardous effects from accidental functioning are confined to within the package. TP27 A portable tank having a minimum test pressure of 4 bar (400 kPa) may be used provided the calculated test pressure is 4 bar or less based on the MAWP of the hazardous material, as defined in 178.275 of this subchapter, where the test pressure is 1.5 times the MAWP. This content is from the eCFR and may include recent changes applied to the CFR. This is in response to your November 18, 2015 e-mail and subsequent conversations with members of my staff requesting clarification of the Hazardous Materials Regulations (HMR; 49 CFR Parts 171-180) applicable to the selection of a . Use the above summary to assist you in reviewing the special provisions applicable to the HazMat you offer for transportation. For criteria in determining what is a new lighter design, see 173.308(b)(1). that, for example, are used for medical, analytical, diagnostic, testing, or repair purposes. 5. B32 MC 312, MC 330, MC 331, DOT 412 cargo tanks and DOT 51 portable tanks must be made of stainless steel, except that steel other than stainless steel may be used in accordance with the provisions of 173.24b(b) of this subchapter. 365 For manufactured instruments and articles containing mercury, see UN3506. Examples of such vehicles are cars, motorcycles, trucks, locomotives, scooters, three- and four-wheeled vehicles or motorcycles, lawn tractors, self-propelled farming and construction equipment, boats, and aircraft. The receptacles must be constructed with glass double walls having the space between the walls vacuum insulated and each receptacle must be transported in an outer packaging with sufficient cushioning and absorbent materials to protect the receptacle from damage. N43 Metal drums are permitted as single packagings only if constructed of nickel or monel. Mixtures containing at least 98%, by mass, of phlegmatizer are not subject to the requirements of this subchapter. This includes vehicles transported in a packaging. Samples taken at random must withstand the prescribed tests without breakage or leakage. N88 Any metal part of a UN pressure receptacle in contact with the contents may not contain more than 65% copper, with a tolerance of 1%. This is an automated process for 422 When labelling is required, the label to be used must be the label shown in 172.447. If it is evident that a package of radioactive material, or conveyance carrying unpackaged radioactive material, is leaking, or if it is suspected that the package, or conveyance carrying unpackaged material, may have leaked, the requirements of 173.443(e) of this subchapter apply. A metal hydride storage system installed in or intended to be installed in a vehicle or equipment or in vehicle or equipment components must be approved for transport by the Associate Administrator. The material is packaged in a DOT Specification 4BW240 cylinder, or in a DOT-51 portable tank. 379 When offered for transport by highway, rail, or cargo vessel, anhydrous ammonia adsorbed or absorbed on a solid contained in ammonia dispensing systems or receptacles intended to form part of such systems is not subject to the requirements of this subchapter if the following conditions in this provision are met. Specification 110A500W tanks must be stainless steel. Except for transportation by aircraft, as an inner packaging of a combination packaging with a maximum net mass of 40 kg (88 pounds). It is shown that it does not pose a significant risk in transportation; b. For transportation by passenger-carrying aircraft, the net mass of lighter refills may not exceed 1 kg per package, and, for cargo-only aircraft, the net mass of lighter refills may not exceed 15 kg per package. The Table: provides the proper shipping name or directs the user to the preferred proper shipping name; For example, nickel-metal hydride batteries transported by vessel in certain quantities are covered by another entry (see Batteries, nickel-metal hydride, UN3496). The coal tar pitch compound must be in a solid mass during transportation. B18 Open steel hoppers or bins are authorized. Column 5 references applicable requirements for bottom openings in part 178 of this subchapter. 238 Neutron radiation detectors: Neutron radiation detectors containing non-pressurized boron trifluoride gas in excess of 1 gram (0.035 ounces) and radiation detection systems containing such neutron radiation detectors as components may be transported by highway, rail, vessel, or cargo aircraft in accordance with the following: a. Dry batteries not specifically covered by another entry in the 172.101 Table are covered by this entry (i.e., Batteries, dry, sealed, n.o.s.) B52 Notwithstanding the provisions of 173.24b of this subchapter, non-reclosing pressure relief devices are authorized on DOT 57 portable tanks. (a) General. (iv) The name or symbol of the bottle producer, and the month and year of manufacture, must be marked by embossing, ink-jet printing of permanent ink, or other permanent means on the face or bottom of each bottle, in letters and numbers at least 6 mm (0.2 inch) high. A Shipper of a hazardous material is responsible for its classification and packaging prior to offering it for shipment to a Carrier. subject to the Hazardous Materials Regulations must comply with all applicable requirements of Subpart F [172.500]. When column 7 of the 172.101 table refers to a special provision for a hazardous material, the meaning and requirements of that provision are as set forth in this section. will also bring you to search results. ; and. TP32 Portable tanks may be used subject to the following conditions: a. the hierarchy of the document. Column 7 of the HMT specifies codes for special provisions applicable to packaging, packaging requirements, certification, and marking or labeling for a hazardous material. This provision may be used for both domestic and international shipments. PDF Special Provision Letter Codes Used in Hazmat Table, Column 7 430 This entry shall only be used for solid medical waste of Category A transported for disposal. No Class 7 label is required to be displayed. If you work for a Federal agency, use this drafting 150 This description may only be used for ammonium nitrate-based fertilizers. Each reference in this column to a material which is a hazardous waste or a hazardous substance, and whose proper shipping name is preceded in Column 1 of the Table by the letter "A" or "W", is modified to include " 173.203" or " 173.213", as appropriate for liquids and solids, respectively, on those occasions when the . When a consignment is undeliverable, the consignment shall be placed in a safe location and the appropriate competent authority shall be informed as soon as possible and a request made for instructions on further action. These detectors must have a minimum burst pressure of 1800 kPa as demonstrated by design type qualification testing; and. 134 This entry applies only to vehicles powered by wet batteries, sodium batteries, lithium metal batteries or lithium ion batteries, and equipment powered by wet batteries or sodium batteries that are transported with these batteries installed. Learn more about the eCFR, its status, and the editorial process. The following tables list, and set forth the requirements of, the special provisions referred to in column 7 of the 172.101 table. W9 When offered for transportation by water, the following Specification packagings are not authorized unless approved by the Associate Administrator: woven plastic bags, plastic film bags, textile bags, paper bags, IBCs and bulk packagings. How to Use Hazmat Special Provisions | Lion Technology For transportation by aircraft, the provisions of 173.159(b)(2) apply. These notes are explained at the end of each TABLE. TP12 This material is considered highly corrosive to steel. B81 Venting and pressure relief devices for tank car tanks and cargo tanks must be approved by the Associate Administrator. or existing codification. Net weight of contents in wooden boxes, barrels or kegs may not exceed 45 kg (99 pounds). Organization and Purpose 148 For domestic transportation, this entry directs to 173.66 for: a. When no IB code is assigned in the 172.101 Table for a specific proper shipping name, or in 173.185 or 173.225(e) Organic Peroxide Table for Type F organic peroxides, use of an IBC or Large Packaging for the material may be authorized when approved by the Associate Administrator. The requirements of 172.203(m) and 172.505 of this subchapter do not apply. In this case, some parts of the vehicle may be detached from its frame to fit into the packaging. 118 This substance may not be transported under the provisions of Division 4.1 unless specifically authorized by the Associate Administrator (see UN0143 or UN0150 as appropriate). 367 For the purposes of documentation and package marking: a. N92 Notwithstanding the provisions of 173.24(g) of this subchapter, packagings shall be designed and constructed to permit the release of gas or vapor to prevent a build-up of pressure that could rupture the packagings in the event of loss of stabilization. 117 If shipment of the explosive substance is to take place at a time that freezing weather is anticipated, the water contained in the explosive substance must be mixed with denatured alcohol so that freezing will not occur. TP21 The wall thickness must not be less than 8 mm. (See 173.50 of this subchapter.). 8 A hazardous substance that is not a hazardous waste may be shipped under the shipping description Other regulated substances, liquid or solid, n.o.s., as appropriate. Transportation by vessel in IBCs is prohibited. B46 The detachable protective housing for the loading and unloading valves of multi-unit tank car tanks must withstand tank test pressure and must be approved by the Associate Administrator. 12 In concentrations greater than 40 percent, this material has strong oxidizing properties and is capable of starting fires in contact with combustible materials. B3 MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo tanks and DOT 57 portable tanks are not authorized. A single packaging of a 4C2 sift-proof, natural wood box; or. The cargo transport unit shall display the UN number in a manner in accordance with 172.332 of this subchapter and be placarded on two opposing sides. The fiber drum must to be fabricated with a three ply wall, as a minimum. Column 7 Lists the additional (special) provisions that apply to this material. Authorized specification bulk outer packagings are UN11G fiberboard intermediate bulk containers (IBC) and UN13H4 woven plastic, coated and with liner flexible intermediate bulk containers (FIBCs) meeting the Packing Group II performance level and lined with a plastic liner of at least 6 mil thickness. B83 Bottom outlets are prohibited on tank car tanks transporting sulfuric acid in concentrations over 65.25 percent. Ammonia solutions may be transported in rigid or composite plastic IBCs (31H1, 31H2 and 31HZ1) that have successfully passed, without leakage or permanent deformation, the hydrostatic test specified in. Choosing an item from 441 For marine pollutants transported under UN3077, Environmentally hazardous substance, solid, n.o.s. or UN3082, Environmentally hazardous substance, liquid, n.o.s. and for purposes of shipping paper and package marking requirements, the technical name used in association with the basic description may be a proper shipping name listed in the 172.101 Hazardous Material Table; provided that the name chosen is not also an entry that includes n.o.s. as a part of the name or one that has a G in column (1) of the table. Insulating materials may not promote corrosion to steel when wet. 53 Packages of these materials must bear the subsidiary risk label, EXPLOSIVE, and the subsidiary hazard class/division must be entered in parentheses immediately following the primary hazard class in the shipping description, unless otherwise provided in this subchapter or through an approval issued by the Associate Administrator, or the competent authority of the country of origin. A34 Aerosols containing a corrosive liquid in Packing Group II charged with a gas are not permitted for transportation by aircraft. PDF 4756 Federal Register /Vol. 88, No. 16/Wednesday, January 25, 2023 Wall thickness must be verified ultrasonically at intervals midway between periodic hydraulic tests (every 2.5 years). If a frangible disc is required in series with the reclosing pressure relief device for the specified portable tank, the alternative portable tank must be fitted with a frangible disc in series with the reclosing pressure relief device; and, (1) When two effective means are specified, the alternative portable tank is fitted with bottom openings having two or three effective means of closure or no bottom openings; or, (2) When three effective means are specified, the portable tank has no bottom openings or three effective means of closure; or. If a tank car tank is equipped with a non-reclosing pressure relief device, the rupture disc must be perforated with a 3.2 mm (0.13 inch) diameter hole. B7 Safety relief devices are not authorized on multi-unit tank car tanks. Hazardous materials necessary for the safe and proper operation of the cargo transport unit (e.g., fire extinguishing systems and air conditioning systems), must be properly secured to or installed in the cargo transport unit and are not otherwise subject to this subchapter. Testing must be conducted on at least three packages as prepared for transport. Retain a copy of each notification of pilot-in-command if requested for up to 30 days Which one of the following hazardous materials is NOT excepted from the quantity limitations in 175.75? These requirements must be met in addition to the design and construction specifications in part 178 of this subchapter. These special provisions are in addition to the standard packaging requirements. Column 7 specifies codes for special provisions applicable to hazardous materials. For liquids transported under ambient conditions may be calculated using the formula: d15 and d50 are the densities (in units of mass per unit volume) of the liquid at 15 C (59 F) and 50 C (122 F), respectively. B115 Rail cars, highway trailers, roll-on/roll-off bins, or other non-specification bulk packagings are authorized. Packages containing mixtures with not less than 90% by mass, of phlegmatizer need not bear a POISON subsidiary risk label. The numbers and letters in the special provisions column are referred to in 49 CFR 172.102 with an explanation of their meanings. A bulk packaging containing sulfur is not subject to the placarding requirements of subpart F of this part, if it is marked with the appropriate identification number as required by subpart D of this part. There you have it! When Column 7 refers to a special provision for a hazardous material, the meaning and requirements of that special provision are as set forth in 172.102 of this subpart. Air must be eliminated from the vapor space by nitrogen or other means. 37 Unless it can be demonstrated by testing that the sensitivity of the substance in its frozen state is no greater than in its liquid state, the substance must remain liquid during normal transport conditions. Quantities of not more than 500 g per package with not less than 10 percent water by mass may also be classed in Division 4.1, provided a negative test result is obtained when tested in accordance with test series 6(c) of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter). Get the latest updates, news, and regulations for HazMat Transport and Waste Management. TP8 A portable tank having a minimum test pressure of 1.5 bar (150 kPa) may be used when the flash point of the hazardous material transported is greater than 0 C (32 F). A hypochlorite solution, UN1791, is a Class 8 corrosive material. 197 The nitrocellulose must meet the criteria of the Bergmann-Junk test or methyl violet paper test in the UN Manual of Tests and Criteria, Appendix 10 (IBR, see 171.7 of this subchapter). B136 Non-specification closed bulk bins are authorized. This entry applies to machinery or apparatus containing hazardous materials as a residue or as an integral element of the machinery or apparatus. B132 Except for transportation by aircraft, UN2813, Water reactive solid, n.o.s. c. A composite packaging 6PG2 (glass, porcelain or stoneware receptacles within a fiberboard box). A37 This entry applies only to a material meeting the definition in 171.8 of this subchapter for self-defense spray. Do not enter until vapors have dissipated. The driver of the transport vehicle and the consignee(s) must be trained not to enter the transport vehicle until the ammonia vapors have dissipated, and the emergency response information on the shipping paper must indicate that the vehicle contains ammonia vapors. 74 During transport, this material must be protected from direct sunshine and stored or kept in a cool and well-ventilated place, away from all sources of heat. 128 Regardless of the provisions of 172.101(c)(12), aluminum smelting by-products and aluminum remelting by-products described under this entry, meeting the definition of Class 8, Packing Group II and III may be classed as a Division 4.3 material and transported under this entry. Model rocket motors containing 30 grams or less propellant are classed as Division 1.4S and items containing more than 30 grams of propellant but not more than 62.5 grams of propellant are classed as Division 1.4C. For transportation of new lighter design samples for examination and testing, see 173.308(b)(2). c. The motor carrier must maintain a satisfactory safety rating as prescribed in 49 CFR part 385. 360 Vehicles powered only by lithium batteries must be described using UN3171, Battery-powered vehicle. Lithium batteries installed in a cargo transport unit, designed only to provide power external to the transport unit, must be described using UN3536, Lithium batteries installed in a cargo transport unit., 361 Capacitors with an energy storage capacity of 0.3 Wh or less are not subject to the requirements of this subchapter. The article, machinery, or apparatus, if unpackaged, or the packaging in which it is contained shall be marked Dangerous goods in articles or Dangerous goods in machinery or Dangerous goods in apparatus as appropriate, with the identification number UN3363. Further, the limitations and/or additional requirements found in the special provisions of column 7 will supersede the packaging authorizations of column 8 of the Hazardous Materials Table. Special provisions contain packaging provisions, prohibitions, exceptions from requirements for particular quantities or forms of materials and requirements or prohibitions applicable to specific modes of transportation, as follows: (1) A code consisting only of numbers (for example, 11) is multi-modal in application and may apply to bulk and non-bulk packagings. In addition to the provisions applicable to the transport of Division 6.1 substances, the provisions of 173.421(c) and 173.443(a) of this subchapter apply. Components classed as Division 6.1, Packing Group I, or Class 8, Packing Group I, must not be offered for transportation and transported under this description. Terminal protection methods include but are not limited to the following: (i) Securely attaching covers of sufficient strength to protect the terminals; (ii) Packaging the battery in a rigid plastic packaging; or. The set to discharge for the spring loaded pressure relief device and the burst pressure for the frangible disc, as applicable, must not be greater than 2.65 bar for portable tanks with minimum test pressures greater than 4 bar; b. Essentially, such SSolder complies with RoHS (Restriction of Hazardous Substances) regulations. Others such as copper and silver are available in trace amounts. Packagings of other material with a small amount of metal, for example metal closures or other metal fittings such as those mentioned in part 178 of this subchapter, are not considered metal packagings. authorized by name in the Hazardous Materials Table or have been specifically authorized by name either in the Section 172.101 Hazardous Materials Table or have been assigned a shipping name and hazard class by the Associate Administrator for Hazardous Materials Safety. 382 Packages containing toy plastic or paper caps for toy pistols described as UN0349, Articles, explosive, n.o.s. Where different hazardous materials in limited quantities are packed together in the same outer packaging, when a gross mass is indicated Column 4 of 173.27 Table 3, the net quantity of each hazardous material must be shown in addition to the gross mass of the completed package. Used or spent dry batteries of both non-rechargeable and rechargeable designs, with a marked rating up to 9-volt that are combined in the same package and transported by highway or rail for recycling, reconditioning, or disposal are not subject to this special provision or any other requirement of the HMR. Lading must be blanketed at all times with a dry inert gas at a pressure not to exceed 103 kPa (15 psig). Each tank car must have a reclosing pressure relief device having a start-to-discharge pressure of 10.34 Bar (150 psig). Lead-free Solder Figure 3: Engineer soldering a microcircuit Note, Tin here is the primary metal. 6 This material is poisonous-by-inhalation and must be described as an inhalation hazard under the provisions of this subchapter. 6. A112 Notwithstanding the quantity limits shown in Column (9A) and (9B) for this entry, the following IBCs are authorized for transportation aboard passenger and cargo-only aircraft. Overview of Hazardous Material Transportation Regulations (3) Damage to terminals. All special provision 352 Ammonium chlorite, ammonium chlorite aqueous solutions, and mixtures of a chlorite with an ammonium salt are forbidden for transport. (Toy caps), 1.4S or NA0337, Toy caps, 1.4S are not subject to the subpart E (labeling) requirements of this part when offered for transportation by motor vehicle, rail freight, cargo vessel, and cargo aircraft and, notwithstanding the packing method assigned in 173.62 of this subchapter, in conformance with the following conditions: a. Outage must be sufficient to prevent tanks from becoming liquid full at 55 C (130 F). A stimulating mechanism must be used to initiate one article in the middle of the packaging. Except when approved by the Associate Administrator, these items may only contain hazardous materials for which exceptions are referenced in Column (8) of the 172.101 Table and are provided in part 173, subparts D and G, of this subchapter. 349 Mixtures of hypochlorite with an ammonium salt are forbidden for transport. TP45 Each portable tank must be made of stainless steel, except that steel other than stainless steel may be used in accordance with the provisions of 173.24b(b) of this subchapter. 420 This entry does not apply to manufactured articles (such as table tennis balls). TP44 Each portable tank must be made of stainless steel, except that steel other than stainless steel may be used in accordance with the provisions of 173.24b(b) of this subchapter. For vessel transport, the palletized loads, pallet boxes or unit load devices must be firmly packed and secured in closed cargo transport units; or. A8 For combination packagings, if glass inner packagings (including ampoules) are used, they must be packed with cushioning material in tightly closed metal receptacles before packing in outer packagings. 62 Oxygen generators (see 171.8 of this subchapter) are not authorized for transportation under this entry. 102 The ends of the detonating cord must be tied fast so that the explosive cannot escape. The mixture for emulsions typically has the following composition: 60-85% ammonium nitrate; 5-30% water; 2-8% fuel; 0.5-4% emulsifier or thickening agent; 0-10% soluble flame suppressants; and trace additives. Hazardous materials not necessary for the safe and proper operation of the cargo transport unit must not be transported within the cargo transport unit. On the basis of the results of suitable burning rate tests, and taking into account the standard tests in the UN Manual of Tests and Criteria, Part III, subsection 33.2.1 (IBR, see 171.7 of this subchapter), nitrocellulose membrane filters in the form in which they are to be transported that do not meet the criteria for a Division 4.1 material are not subject to the requirements of this subchapter. a. Each special provision is indicated using a numeric or alphanumeric code. B4 MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo tanks are not authorized. g. The test results shall be documented, shall be traceable, and shall be made available to a representative of the Department upon request. When column 7 of the Hazardous Materials Table (49 CFR 172.101) includes a special provision code for an entry in the table, the requirement of that code - or codes, there may be several of them - is in addition to the general packaging requirements of 173.24 and any other applicable packaging requirements in Part 173. b. This training must be documented in training records required by 172.704(d). This entry may not be used for solids containing a Packing Group I liquid. Portable tanks containing solidified methacrylic acid must not be reheated during transportation. Insulation must be at least 100 mm (3.9 inches) except that the insulation thickness may be reduced to 51 mm (2 inches) over the exterior heater coils. 370 This entry also applies to ammonium nitrate with not more than 0.2% combustible substances, including any organic substance calculated as carbon, to the exclusion of any added substance, that gives a positive result when tested in accordance with Test Series 2 of the UN Manual of Tests and Criteria, Part I (IBR; see 171.7 of this subchapter). These provisions apply only to transportation in IBCs and Large Packagings. If a fuel cell engine is installed in a vehicle, the vehicle must be described using Vehicle, fuel cell, flammable gas powered or Vehicle, fuel cell, flammable liquid powered, as appropriate. 50 Cases, cartridge, empty with primer which are made of metallic or plastic casings and meeting the classification criteria of Division 1.4 are not regulated for domestic transportation. Formaldehyde solutions not containing methanol and not meeting the Class 3 flammable liquid criteria must be described using a different proper shipping name. What does the sign in column 1 of the hazardous materials Table mean TP37 IM portable tanks are only authorized for the shipment of hydrogen peroxide solutions in water containing 72% or less hydrogen peroxide by weight. Openings for safety relief devices on multi-unit tank car tanks shall be plugged or blank flanged. A4 Liquids having an inhalation toxicity of Packing Group I are not permitted on aircraft. When phlegmatized with water and inorganic inert material, the content of urea nitrate must not exceed 75 percent by mass and the mixture should not be capable of being detonated by test 1(a)(i) or test 1(a)(ii) in the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter). The means of protection must be approved by the approval agency designated to approve the portable tank in accordance with the procedures in part 107, subpart E, of this subchapter. Determining Authorized Packaging for the Transportation of a Hazardous Portable tanks must be hydraulically tested and internally inspected at intervals not exceeding 2.5 years. Note 1: Based on maximum lading pressure of 1 psig at top of cargo tank. B59 Water-tight, sift-proof, closed-top, metal-covered hopper cars are also authorized provided that the lading is covered with a nitrogen blanket. d. The proper shipping name Printing ink related material may be used for consignments of packages containing Printing ink and Printing ink related material in the same package.

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